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Forward osmosis coupled with lime-soda ash softening for volume minimization of reverse osmosisconcentrate and CaCO3 recovery: A case study on the coal chemical

Jiandong Lu, Shijie You, Xiuheng Wang

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1301-6

摘要： Abstract • Forward osmosis (FO) coupled with chemical softening for CCI ROC minimization • Effective removal of scale precursor ions by lime-soda ash softening • Enhanced water recovery from 54% to 86% by mitigation of FO membrane scaling • High-purity CaCO3 was recovered from the softening sludge • Membrane cleaning efficiency of 88.5% was obtained by EDTA for softened ROC Reverse osmosis (RO) is frequently used for water reclamation from treated wastewater or desalination plants. The RO concentrate (ROC) produced from the coal chemical industry (CCI) generally contains refractory organic pollutants and extremely high-concentration inorganic salts with a dissolved solids content of more than 20 g/L contributed by inorganic ions, such as Na+, Ca2+, Mg2+, Cl−, and SO42−. To address this issue, in this study, we focused on coupling forward osmosis (FO) with chemical softening (FO-CS) for the volume minimization of CCI ROC and the recovery of valuable resources in the form of CaCO3. In the case of the real raw CCI ROC, softening treatment by lime-soda ash was shown to effectively remove Ca2+/Ba2+ (>98.5%) and Mg2+/Sr2+/Si (>80%), as well as significantly mitigate membrane scaling during FO. The softened ROC and raw ROC corresponded to a maximum water recovery of 86% and 54%, respectively. During cyclic FO tests (4 × 10 h), a 27% decline in the water flux was observed for raw ROC, whereas only 4% was observed for softened ROC. The cleaning efficiency using EDTA was also found to be considerably higher for softened ROC (88.5%) than that for raw ROC (49.0%). In addition, CaCO3 (92.2% purity) was recovered from the softening sludge with an average yield of 5.6 kg/m3 treated ROC. This study provides a proof-of-concept demonstration of the FO-CS coupling process for ROC volume minimization and valuable resources recovery, which makes the treatment of CCI ROC more efficient and more economical.

关键词： Coal chemical industry     Forward osmosis     Chemical softening     Reverse osmosis concentrate    

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Correlation between tension softening relation and crack extension resistance in concrete

Xiufang ZHANG , Shilang XU ,

《结构与土木工程前沿（英文）》 2009年 第3卷 第3期   页码 323-329 doi: 10.1007/s11709-009-0041-2

摘要： Changes of the material fracture energy consumption with crack propagation can be described by a crack extension resistance curve, one of the fundamental fracture criteria in crack mechanics. Recently, experimental observation of the fracture behavior in concrete was used to develop a new fracture criterion, the crack extension resistance curve, to analyze crack propagation during the entire concrete fracture process. The variation of the crack extension resistance is mainly associated with the energy consumption in the fracture process zone ahead of the stress-free crack tip. The crack extension resistance is then a function of the softening curve, which is a basic mechanical property in the fracture process zone. The relationship between the softening curve and the crack extension resistance curve is then analyzed based on results of three-point bending beams tests. The results indicate that the characteristic points of the crack extension resistance curve is closely related to the characteristic point on used tension softening curve.

关键词： concrete     fracture process zone     crack extension GR resistance     tension softening curve    

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Soil-water interaction in unsaturated expansive soil slopes

ZHAN Liangtong

《结构与土木工程前沿（英文）》 2007年 第1卷 第2期   页码 198-204 doi: 10.1007/s11709-007-0023-1

摘要： The intensive soil-water interaction in unsaturated expansive soil is one of the major reasons for slope failures. In this paper, the soil-water interaction is investigated with the full-scale field inspection of rainwater infiltration and comprehensive experiments, including wetting-induced softening tests, swelling, and shrinkage tests. It is demonstrated that the soil-water interaction induced by seasonal wetting-drying cycles is very complex, and it involves coupled effects among the changes in water content, suction, stress, deformation and shear strength. In addition, the abundant cracks in the expansive soil play an important role in the soil-water interaction. The cracks disintegrate the soil mass, and more importantly, provide easy pathways for rainfall infiltration. Infiltration of rainwater not only results in wetting-induced softening of the shallow unsaturated soil layers, but also leads to the increase of horizontal stress. The increase of horizontal stress may lead to a local passive failure. The seasonal wetting-drying cycles tend to result in a down-slope creeping of the shallow soil layer, which leads to progressive slope failure.

关键词： strength     intensive soil-water     comprehensive     Infiltration     wetting-induced softening    

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薄板坯连铸连轧铁素体+珠光体类型钢的强化与软化

傅杰,吴华杰,刘阳春

《中国工程科学》 2008年 第10卷 第4期   页码 65-72

摘要：

根据钢的综合强化理论，控制A1附近温度下钢中碳的析出，研究了HSLC钢的强化与软化问题。结果表明：薄板坯连铸连轧HSLC钢，强度还可进一步提高；通过回火缓冷，薄板坯连铸连轧HSLC钢ZJ330的σs从344 MPa降至225 MPa，能满足冷轧基板要求。讨论了有关铁素体轧制、超细晶粒钢以及一种可能的新型建筑材料等问题。

关键词： HSLC钢     强化     软化     冷轧基板     超级钢    

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Special issue on “Green chemical process and intensification”

《化学科学与工程前沿（英文）》 2022年 第16卷 第11期   页码 1533-1535 doi: 10.1007/s11705-022-2263-y

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Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 775-776 doi: 10.1007/s11705-022-2172-0

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Insight of chemical environmental risk and its management from the vinyl chloride accident

《环境科学与工程前沿（英文）》 2023年 第17卷 第4期 doi: 10.1007/s11783-023-1652-x

摘要： The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023 has caused widespread concern around the world. This paper tried to analyze several issues concerning the accident, including the appropriateness of the VC combustion in the emergency response in this accident, the meanings of so-called “controlled combustion”, the potential environmental risks caused by VC and combustion by-products, and follow-up work. In our view, this accident had surely caused environmental and health risks to some extent. Hence, a comprehensive environmental risk assessment is necessary, and then the site with risk should be comprehensively remediated, hazardous waste should be harmlessly treated as soon as possible. Finally, this accident suggests that further efforts should be taken to bridge the gap between chemical safety management and their environmental risk management.

关键词： Vinyl chloride     Combustion     Chemical safety management     Environmental risk     Emerging contaminants    

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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1728-7

摘要：

● A higher sulfur content reduced the curing rate of Cr in glass.

关键词： Dechlorinated fly ash     SO3     Heavy metal     Chemical speciation     Glass solidification    

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我国林产化学工业发展的新动向

宋湛谦

《中国工程科学》 2001年 第3卷 第2期   页码 1-6

摘要：

林产化学工业是将可再生的森林资源经过化学加工生产出各种有用的产品。它是森林资源高效可持续利用的一个重要组成部分。文章介绍我国林产化学工业的现状，并指出今后发展方向，即加强创新研究，开发深加工产品；推进林产化工企业向大型化发展；发展木材制浆造纸和开发木质能源。

关键词： 林产化学工业     森林资源     化学加工    

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Bioinspired and biomimetic membranes for water purification and chemical separation: A review

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1412-8

摘要：

•The history of biological and artificial water channels is reviewed.

关键词： Aquaporins     Artificial water channels     Biomimetic membranes     Chemical separation and water purification    

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Chemical transdifferentiation: closer to regenerative medicine

null

《医学前沿（英文）》 2016年 第10卷 第2期   页码 152-165 doi: 10.1007/s11684-016-0445-z

摘要：

Cell transdifferentiation, which directly switches one type of differentiated cells into another cell type, is more advantageous than cell reprogramming to generate pluripotent cells and differentiate them into functional cells. This process is crucial in regenerative medicine. However, the cell-converting strategies, which mainly depend on the virus-mediated expression of exogenous genes, have clinical safety concerns. Small molecules with compelling advantages are a potential alternative in manipulating cell fate conversion. In this review, we briefly retrospect the nature of cell transdifferentiation and summarize the current developments in the research of small molecules in promoting cell conversion. Particularly, we focus on the complete chemical compound-induced cell transdifferentiation, which is closer to the clinical translation in cell therapy. Despite these achievements, the mechanisms underpinning chemical transdifferentiation remain largely unknown. More importantly, identifying drugs that induce resident cell conversion in vivo to repair damaged tissue remains to be the end-goal in current regenerative medicine.

关键词： cell therapy     cell transdifferentiation     chemical compounds     small molecules     tissue regeneration    

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Computational design of structured chemical products

Faheem Mushtaq, Xiang Zhang, Ka Y. Fung, Ka M. Ng

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1033-1049 doi: 10.1007/s11705-020-2002-1

摘要： In chemical product design, the aim is to formulate a product with desired performance. Ingredients and internal product structure are two key drivers of product performance with direct impact on the mechanical, electrical, and thermal properties. Thus, there is a keen interest in elucidating the dependence of product performance on ingredients, structure, and the manufacturing process to form the structure. Design of product structure, particularly microstructure, is an intrinsically complex problem that involves different phases of different physicochemical properties, mass fraction, morphology, size distribution, and interconnectivity. Recently, computational methods have emerged that assist systematic microstructure quantification and prediction. The objective of this paper is to review these computational methods and to show how these methods as well as other developments in product design can work seamlessly in a proposed performance, ingredients, structure, and manufacturing process framework for the design of structured chemical products. It begins with the desired target properties and key ingredients. This is followed by computation for microstructure and then selection of processing steps to realize this microstructure. The framework is illustrated with the design of nanodielectric and die attach adhesive products.

关键词： product design     performance     ingredients     structure     manufacturing process framework     structured chemical products     microstructure design    

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Hexachlorobutadiene emissions from typical chemical plants

Minxiang Wang, Lili Yang, Xiaoyun Liu, Zheng Wang, Guorui Liu, Minghui Zheng

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1352-8

摘要： Abstract • Unintentional HCBD production in typical chemical plants was investigated. • The highest HCBD concentrations were found in the bottom residue. • Tri/tetrachloroethylene production processes were important HCBD sources. Hexachlorobutadiene (HCBD) was classed as a persistent organic pollutant under the Stockholm Convention in 2015. HCBD is mainly an unintentionally produced by-product of chlorinated hydrocarbon (e.g., trichloroethylene and tetrachloroethylene) synthesis. Few studies of HCBD formation during chemical production processes have been performed, so HCBD emissions from these potentially important sources are not understood. In this study, HCBD concentrations in raw materials, intermediate products, products, and bottom residues from chemical plants producing chlorobenzene, trichloroethylene, and tetrachloroethylene were determined. The results indicated that HCBD is unintentionally produced at much higher concentrations in trichloroethylene and tetrachloroethylene plants than chlorobenzene plants. The sum of the HCBD concentrations in the samples from all of the trichloroethylene and tetrachloroethylene production stages in plant PC was 247000 mg/mL, about three orders of magnitude higher than the concentrations in the tetrachloroethylene production samples (plant PB) and about six orders of magnitude higher than the concentrations in the chlorobenzene production samples (plant PA). The HCBD concentrations were highest in bottom residues from all of the plants. The concentrations in the bottom residue samples contributed 24%–99% of the total HCBD formed in the chemical production plants. The bottom residue, being hazardous waste, could be disposed of by incineration. The HCBD concentrations were much higher in intermediate products than raw materials, indicating that HCBD formed during production of the intended chemicals. The results indicate the concentrations of HCBD unintentionally produced in typical chemical plants and will be useful in developing protocols for controlling HCBD emissions to meet the Stockholm Convention requirements.

关键词： Hexachlorobutadiene     Chemical plant     Chlorobenzene     Trichloroethylene     Tetrachloroethylene    

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Opportunities and challenges for a Golden Age of chemical engineering

Phillip R. WESTMORELAND

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 1-7 doi: 10.1007/s11705-014-1416-z

摘要： Chemical engineering is entering a new Golden Age of practice, thought, and impact, accompanied by great new opportunities and challenges. Five aspects mark this development: a new abundance of hydrocarbons; the evolution of biology into a molecular science; the ubiquity of powerful computational tools; the trend in manufacturing to be more process-oriented; and the systems approach that is part of ChE education from its first stages. There are important technical challenges, including technology creation and environmental impact, but just as important are new appreciation for and attention to challenges that require societal dialogues about complexity, uncertainty, and evolving and sometimes contradictory requirements. Crucial to all these impacts is enhancing the identity of what the profession is. That must be based on recognizing that the core of chemical engineering is applying molecular sciences to create value and advance the quality of life.

关键词： hydrocarbons     biotechnology     computation     cyberinfrastructure     manufacturing     environmental    

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Two-dimensional numerical and eco-toxicological modeling of chemical spills

Suiliang HUANG, Yafei JIA, Sam S. Y. WANG

《环境科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 178-185 doi: 10.1007/s11783-009-0020-9

摘要： The effects of chemical spills on aquatic non-target organisms were evaluated in this study. Based on a review of three types of current eco-toxicological models of chemicals, i.e., ACQUATOX model of the US-EPA, Hudson River Model of PCBs, and critical body residual (CBR) model and dynamic energy budget (DEBtox) model, this paper presents an uncoupled numerical eco-toxicological model. The transport and transformation of spilled chemicals were simulated by a chemical transport model (including flow and sediment transport), and the mortalities of an organism caused by the chemicals were simulated by the extended threshold damage model, separately. Due to extreme scarcity of data, this model was applied to two hypothetical cases of chemical spills happening upstream of a lake. Theoretical analysis and simulated results indicated that this model is capable of reasonably predicting the acute effects of chemical spills on aquatic ecosystems or organism killings.

关键词： chemical spills     acute effects     aquatic ecosystem     eco-toxicological modeling    

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标题 作者 时间 类型 操作

Forward osmosis coupled with lime-soda ash softening for volume minimization of reverse osmosisconcentrate and CaCO3 recovery: A case study on the coal chemical

Jiandong Lu, Shijie You, Xiuheng Wang

期刊论文

Correlation between tension softening relation and crack extension resistance in concrete

Xiufang ZHANG , Shilang XU ,

期刊论文

Soil-water interaction in unsaturated expansive soil slopes

ZHAN Liangtong

期刊论文

薄板坯连铸连轧铁素体+珠光体类型钢的强化与软化

傅杰,吴华杰,刘阳春

期刊论文

Special issue on “Green chemical process and intensification”

期刊论文

Special Issue for the Future Chemical Engineering Scholars of Global Chinese Chemical Engineering Symposium

期刊论文

Insight of chemical environmental risk and its management from the vinyl chloride accident

期刊论文

Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

期刊论文

我国林产化学工业发展的新动向

宋湛谦

期刊论文

Bioinspired and biomimetic membranes for water purification and chemical separation: A review

期刊论文

Chemical transdifferentiation: closer to regenerative medicine

null

期刊论文

Computational design of structured chemical products

Faheem Mushtaq, Xiang Zhang, Ka Y. Fung, Ka M. Ng

期刊论文

Hexachlorobutadiene emissions from typical chemical plants

Minxiang Wang, Lili Yang, Xiaoyun Liu, Zheng Wang, Guorui Liu, Minghui Zheng

期刊论文

Opportunities and challenges for a Golden Age of chemical engineering

Phillip R. WESTMORELAND

期刊论文

Two-dimensional numerical and eco-toxicological modeling of chemical spills

Suiliang HUANG, Yafei JIA, Sam S. Y. WANG

期刊论文